Bismuth Trichloride MSDS

Section 1: Chemical Product and Company Identification

Product Name: Bismuth Trichloride

Catalog Codes: SLB4615

CAS#: 787-60-2

RTECS: EB2690000

TSCA: TSCA 8(b) inventory: Bismuth Trichloride

CI#: Not available.

Synonym: Bismuth Trichloride; Trichlorobismuth;

Trichlorobismuthine;

Chemical Name: Bismuth Trichloride

Chemical Formula: Bi-Cl3

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Bismuth Trichloride 787-60-2 100

Toxicological Data on Ingredients: Bismuth Trichloride: ORAL (LD50): Acute: 3334 mg/kg [Rat]. 2250 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion. Hazardous in case of

inhalation. Slightly hazardous in case of skin contact (corrosive), of eye contact (corrosive). The amount of tissue

damage depends on length of contact. Eye contact can result in corneal damage or blindness. Skin contact can

produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal or respiratory

tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage,

choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching.

Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP, None. by OSHA, None. by NIOSH.

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available.

The substance may be toxic to mucous membranes, skin, eyes.

Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure of the

eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction,

or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at

least 15 minutes. Get medical attention immediately.

Skin Contact:

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated

clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean

shoes before reuse. Get medical attention immediately.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical

attention.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

medical attention immediately.

Serious Inhalation: Not available.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an

unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if

symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available.

Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by

spreading water on the contaminated surface and dispose of according to local and regional authority

requirements.

Large Spill:

Corrosive solid.

Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to

reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on

disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the

sanitary system.

Section 7: Handling and Storage

Precautions:

Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient

ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the

container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing

agents, acids, alkalis, moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below

recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to

airborne contaminants below the exposure limit.

Personal Protection:

Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or

equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus

should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a

specialist BEFORE handling this product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystalline solid.)

Odor: Acetic acid. (Slight.)

Taste: Not available.

Molecular Weight: 315.34 g/mole

Color: White to yellowish.

pH (1% soln/water): Not available.

Boiling Point: 447°C (836.6°F)

Melting Point: 227°C (440.6°F)

Critical Temperature: Not available.

Specific Gravity: 456 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water, methanol, diethyl ether, acetone.

Solubility: Soluble in methanol, diethyl ether, acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Reactive with reducing agents, acids, alkalis, moisture.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 2250 mg/kg [Mouse].

Chronic Effects on Humans:

CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP, None. by OSHA, None. by NIOSH.

May cause damage to the following organs: mucous membranes, skin, eyes.

Other Toxic Effects on Humans:

Very hazardous in case of skin contact (irritant), of ingestion.

Hazardous in case of inhalation.

Slightly hazardous in case of skin contact (corrosive), of eye contact (corrosive).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects:

Skin: Causes severe irritation and possible burns.

Eyes: Causes severe irritation and possible burns.

Inhalation: Causes irritation of of the respiratory tract and mucous membranes.

Ingestion: Bismuth compounds can cause severe irritation of the gastrointestinal tract with nausea, cramping,

diarrhea, vomiting. May cause colitis, gastrointestinal bleeding, corrosion and permanent tissue destruction of the

esophagus and digestive tract. Bismuth compounds are poorly absorbed. However, should absorption occur,

exposure may cause loss of appetite, kidney toxicity/damage (albuminuria, hematuria, nephritis), liver

toxicity/damage (jaundic, hepatitis), methemoglobinemia.

Chronic Potential Health Effects:

Repeated or prolonged exposure to Bismuth or Bismuth compounds may cause a Bismuth (metal) line or black

spots on the gums, foul breath, gingivitis, ulcerative stomatitis, nausea, vomiting, diarrhea, salivation, loss of

appetite and weight, headache, depression, impaired memory, incoordination, muscle twitching, sleeplessness,

lethargy, paranoia, joint pain, liver and kidney damage. Due to the presence of dark line on gums, chronic

bismuth toxicity may complicate diagnosis of chronic lead toxicity. The highest levels of Bismuth are found in the

kidney and liver. It can replace Lead in the body, such that persons with large stores of lead from previous

exposures can have recurring signs of Lead poisoning after exposure to Bismuth. Other symptoms of Bismuth

poisoning may include agranulocytosis, and aplastic anemia

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may

arise.

Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in accordance with federal, state and local environmental

control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Corrosive solid, acidic, inorganic, n.o.s (Bismuth (III) Chloride) UNNA: 3260 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Bismuth Chloride

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):

R34- Causes burns.

S26- In case of contact with eyes, rinse

immediately with plenty of water and seek

medical advice.

S28- After contact with skin, wash immediately

with plenty of water.

S36- Wear suitable protective clothing.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

Personal Protection: j

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:

Protective Equipment:

Gloves.

Synthetic apron.

Vapor and dust respirator. Be sure to

use an approved/certified respirator or

equivalent.

Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 04:23 PM

Last Updated: 11/06/2008 12:00 PM