MSDS Number: H6815 * * * * * Effective Date: 11/21/08 * * * * * Supercedes: 01/13/06 HYDROXY NAPHTHOL BLUE


HYDROXY NAPHTHOL BLUE


1. Product Identification

Synonyms: 1-(2-naphtholazo-3, 6-disulfonic acid)-2-naphthol-4-sulfonic acid trisodium salt; calcium ç on sodium chloride
CAS No.: 7647-14-5 Sodium chloride 63451-35-4 Hydroxy naphthol blue
Molecular Weight: Not applicable to mixtures.
Chemical Formula: Not applicable to mixtures.
Product Codes:
J.T. Baker: N719, N720
Mallinckrodt: 5630

2. Composition/Information on Ingredients


 
  Ingredient                                CAS No         Percent        Hazardous                                  
  ---------------------------------------   ------------   ------------   ---------   
 
  Sodium Chloride                           7647-14-5          > 99%         Yes                                                                  
  Hydroxy Naphthol Blue                     63451-35-4         < 1%          No                                                                  
 

3. Hazards Identification

Emergency Overview
--------------------------
WARNING! CAUSES EYE IRRITATION.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)
-----------------------------------------------------------------------------------------------------------
Health Rating: 1 - Slight
Flammability Rating: 0 - None
Reactivity Rating: 0 - None
Contact Rating: 1 - Slight
Lab Protective Equip: GOGGLES; LAB COAT; PROPER GLOVES
Storage Color Code: Green (General Storage)
-----------------------------------------------------------------------------------------------------------

Potential Health Effects
----------------------------------

Inhalation:
May cause mild irritation to the respiratory tract.
Ingestion:
Very large doses can cause vomiting, diarrhea, and prostration. Dehydration and congestion occur in most internal organs. Hypertonic salt solutions can produce violent inflammatory reactions in the gastrointestinal tract.
Skin Contact:
May irritate damaged skin; absorption can occur with effects similar to those via ingestion.
Eye Contact:
Causes irritation, redness, and pain. (For salt concentrations greater than the normal saline present.)
Chronic Exposure:
No information found.
Aggravation of Pre-existing Conditions:
No information found.

4. First Aid Measures

Inhalation:
Remove to fresh air. Get medical attention for any breathing difficulty.
Ingestion:
If large amounts were swallowed, give water to drink and get medical advice.
Skin Contact:
Wash exposed area with soap and water. Get medical advice if irritation develops.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.

5. Fire Fighting Measures

Fire:
Not considered to be a fire hazard.
Explosion:
Not considered to be an explosion hazard.
Fire Extinguishing Media:
Use any means suitable for extinguishing surrounding fire.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Sweep up and containerize for reclamation or disposal. Vacuuming or wet sweeping may be used to avoid dust dispersal.



7. Handling and Storage

Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
None established.
Ventilation System:
In general, dilution ventilation is a satisfactory health hazard control for this substance. However, if conditions of use create discomfort to the worker, a local exhaust system should be considered.
Personal Respirators (NIOSH Approved):
For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P filter. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres.
Skin Protection:
Wear protective gloves and clean body-covering clothing.
Eye Protection:
Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance:
Blue crystals.
Odor:
Odorless.
Solubility:
Soluble in water.
Density:
No information found.
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0 (Sodium chloride).
Boiling Point:
1413C (2575F) (Sodium chloride).
Melting Point:
801C (1474F) (Sodium chloride).
Vapor Density (Air=1):
No information found.
Vapor Pressure (mm Hg):
1.0 @ 865C (1589F) (Sodium chloride).
Evaporation Rate (BuAc=1):
No information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage. Hygroscopic.
Hazardous Decomposition Products:
When heated to decomposition it emits toxic fumes of nitrogen oxides and hydrogen chloride.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
For Sodium Chloride: Lithium, bromine trifluoride.
Conditions to Avoid:
Incompatibles.

11. Toxicological Information


Sodium Chloride : Oral rat LD50: 3000 mg/kg. Standard Draize, rabbit, eye: 100mg/24hr moderate irritant. Investigated as a mutagen and reproductive effector.
 
  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Sodium Chloride (7647-14-5)             No          No            None
  Hydroxy Naphthol Blue (63451-35-4)      No          No            None

12. Ecological Information

Environmental Fate:
No information found.
Environmental Toxicity:
No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Not regulated.

15. Regulatory Information

 
  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Sodium Chloride (7647-14-5)                       Yes  Yes   Yes      Yes                                      
  Hydroxy Naphthol Blue (63451-35-4)                Yes  Yes   No       Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Sodium Chloride (7647-14-5)                       Yes   Yes   No     Yes        
  Hydroxy Naphthol Blue (63451-35-4)                No    Yes   No     Yes               
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Sodium Chloride (7647-14-5)                No    No      No         No
  Hydroxy Naphthol Blue (63451-35-4)         No    No      No         No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Sodium Chloride (7647-14-5)                No         No         No      
  Hydroxy Naphthol Blue (63451-35-4)         No         No         No             
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  No     CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: No   Fire: No  Pressure: No
Reactivity: No          (Mixture / Solid)


Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0
Label Hazard Warning:
WARNING! CAUSES EYE IRRITATION.
Label Precautions:
Avoid contact with eyes.
Wash thoroughly after handling.
Label First Aid:
In case of eye contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists.
Product Use:
Laboratory Reagent.
Revision Information:
No Changes.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)