Ferrous Bromide (iron (II) bromide) MSDS

Section 1: Chemical Product and Company Identification

Product Name: Ferrous Bromide (iron (II) bromide)

Catalog Codes: SLA4201

CAS#: 7727-15-3

RTECS: BD0350000

TSCA: TSCA 8(b) inventory: Ferrous Bromide (iron (II) bromide)

CI#: Not available.

Synonym:

Chemical Name: Ferrous Bromide (iron (II) bromide)

Chemical Formula: Al-Br3

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Ferrous Bromide (iron (II) bromide) 7727-15-3 100

Toxicological Data on Ingredients: Ferrous Bromide (iron (II) bromide): ORAL (LD50): Acute: 1598 mg/kg [Rat]. 1623 mg/kg

[Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation (lung irritant). Corrosive to

eyes and skin. The amount of tissue damage depends on length of contact. Eye contact can result in corneal

damage or blindness. Skin contact can produce inflammation and blistering. Severe over-exposure can produce

lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness, watering,

and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH. (Inadequate study.) by NTP.

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available.

Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can

produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of

respiratory irritation or lung damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at

least 15 minutes. Get medical attention immediately.

Skin Contact:

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated

clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean

shoes before reuse. Get medical attention immediately.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate

medical attention.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

medical attention immediately.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or

waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth

resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation

when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an

unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight

clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available.

Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill:

Corrosive solid.

Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to

reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on

disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS

and with local authorities.

Section 7: Handling and Storage

Precautions:

Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case of insufficient

ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the

container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as acids, moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below

recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to

airborne contaminants below the exposure limit.

Personal Protection:

Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or

equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus

should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a

specialist BEFORE handling this product.

Exposure Limits:

TWA: 10 (mg/m3) from ACGIH (TLV) [United States]

TWA: 10 from NIOSH Respirable.

Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.

Odor: Not available.

Taste: Not available.

Molecular Weight: 266.7 g/mole

Color: White to yellowish.

pH (1% soln/water): Not available.

Boiling Point: 265°C (509°F)

Melting Point: 97.5°C (207.5°F)

Critical Temperature: Not available.

Specific Gravity: 3.205 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties:

Dispersed in methanol.

Partially dispersed in diethyl ether.

See solubility in water, methanol, diethyl ether, acetone.

Solubility:

Soluble in methanol.

Partially soluble in diethyl ether, acetone.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances:

Extremely reactive or incompatible with moisture.

Reactive with acids.

Corrosivity: Not available.

Special Remarks on Reactivity: Reacts Violently with Water

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.

Toxicity to Animals: Acute oral toxicity (LD50): 1598 mg/kg [Rat].

Chronic Effects on Humans: CARCINOGENIC EFFECTS: Classified None. by OSHA, None. by NIOSH. (Inadequate study.)

by NTP.

Other Toxic Effects on Humans:

Very hazardous in case of skin contact (irritant), of inhalation (lung irritant).

Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of inhalation (lung corrosive).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may

arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Aluminum Bromide, Anhydrous UNNA: UN1725 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

California prop. 65: This product contains the following ingredients for which the State of California has found to

cause cancer, birth defects or other reproductive harm, which would require a warning under the statute:

Aluminum Bromide, anhydrous

Pennsylvania RTK: Aluminum Bromide, anhydrous

Minnesota: Aluminum Bromide, anhydrous

Massachusetts RTK: Aluminum Bromide, anhydrous

New Jersey: Aluminum Bromide, anhydrous

TSCA 8(b) inventory: Aluminum Bromide, anhydrous

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): CLASS E: Corrosive solid.

DSCL (EEC):

R22- Harmful if swallowed.

R34- Causes burns.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

Personal Protection: j

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:

Protective Equipment:

Gloves.

Synthetic apron.

Vapor and dust respirator. Be sure to

use an approved/certified respirator or

equivalent. Wear appropriate respirator

when ventilation is inadequate.

Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 03:40 PM

Last Updated: 11/06/2008 12:00 PM