Menadione Sodium Bisulfite Pure MSDS

Section 1: Chemical Product and Company Identification

Product Name: Menadione Sodium Bisulfite Pure

Catalog Codes: SLM4309

CAS#: 57414-02-5 or 130-37-0

RTECS: QK3682000

TSCA: TSCA 8(b) inventory: Menadione Sodium Bisulfite Pure

CI#: Not available.

Synonym: VitaminKinjection;VitaminK3sodiumbisulfite;

Klotogen; 2-Methyl-1,4-naphthoquinone - Sodium Bisulfite;

2-Naphthalenesulfonic acid,

1,2,3,4-tetrahydro-2-methyl-1,4-dioxo-, sodium salt

Chemical Name: Menadione Sodium Bisulfite Pure

Chemical Formula: C11-H9-O5-S.Na

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Menadione Sodium Bisulfite Pure 57414-02-5 or 100

130-37-0

Toxicological Data on Ingredients: Menadione Sodium Bisulfite Pure LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation

(lung irritant).

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC.

MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.

TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available.

The substance is toxic to kidneys, lungs, liver, mucous membranes.

Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at

least 15 minutes. Cold water may be used. Get medical attention.

Skin Contact:

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove

contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes

before reuse. Get medical attention.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical

attention.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

medical attention.

Serious Inhalation: Not available.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an

unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight

clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: CLOSED CUP: Higher than 93.3°C (200°F).

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2), sulfur oxides (SO2, SO3...).

Fire Hazards in Presence of Various Substances:

Slightly flammable to flammable in presence of open flames and sparks, of heat.

Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available.

Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder.

LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by

spreading water on the contaminated surface and dispose of according to local and regional authority

requirements.

Large Spill:

Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water

on the contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:

Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,

evaporate the residue under a fume hood. Ground all equipment containing material. Do not breathe dust. Wear

suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If you feel

unwell, seek medical attention and show the label when possible. Avoid contact with skin and eyes.

Storage:

Light Sensitive. Moisture Sensitive. Store in light-resistant containers. Keep container tightly closed. Keep

container in a cool, well-ventilated area. Do not store above 24°C (75.2°F). Preferably refrigerate and do not

store above 0 C (32 F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below

recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to

airborne contaminants below the exposure limit.

Personal Protection:

Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.

Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used

to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist

BEFORE handling this product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystals solid.)

Odor: Slight.

Taste: Not available.

Molecular Weight: 276.25 g/mole

Color: Yellow. White. (Light.)

pH (1% soln/water): Not available.

Boiling Point: Not available.

Melting Point: Decomposes.

Critical Temperature: Not available.

Specific Gravity: Not available.

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility: Soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Excess heat, incompatible materials

Incompatibility with various substances: Not available.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:

May decompose on exposure to light.

Protect from moisture

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals:

LD50: Not available.

LC50: Not available.

Chronic Effects on Humans:

CARCINOGENIC EFFECTS: 3 (Not classifiable for human.) by IARC.

MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.

Causes damage to the following organs: kidneys, lungs, liver, mucous membranes.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: May affect genetic material based on laboratory tests.

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects:

Skin: May cause irritation and/or allergic reaction.

Eyes: May cause eye irritation and slight corneal damage

Ingestion: May cause gastrointestinal tract irritation.

Inhalation: Inhalation of excessive dusts may cause irritation of the upper respiratory tract and mucous

membranes.

Chronic Potential Health Effects: May affect metabolism and cardiovascular system.

The toxicological properties of this substance have not been fully investigated.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may

arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in accordance with federal, state and local environmental

control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Menadione-sodium bisulfite

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):

R36/37/38- Irritating to eyes,

respiratory system and skin.

S26- In case of contact with eyes, rinse

immediately with plenty of water and seek

medical advice.

S36/37- Wear suitable protective clothing and

gloves.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves.

Lab coat.

Dust respirator. Be sure to use an

approved/certified respirator or

equivalent.

Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 06:04 PM

Last Updated: 11/06/2008 12:00 PM