Nickel (Metal) Powder 99.8% MSDS

Section 1: Chemical Product and Company Identification

Product Name: Nickel (Metal) Powder 99.8%

Catalog Codes: SLN2296, SLN1342, SLN1954

CAS#: 7440-02-0

RTECS: QR5950000

TSCA: TSCA 8(b) inventory: Nickel (Metal) Powder 99.8%

CI#: Not applicable.

Synonym: Nickel Metal shot; Nickel metal foil.

Chemical Name: Nickel

Chemical Formula: Ni

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Nickel (Metal) Powder 99.8% 7440-02-0 100

Toxicological Data on Ingredients: Nickel metal LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant, sensitizer), of eye contact

(irritant), of ingestion.

Potential Chronic Health Effects:

Slightly hazardous in case of skin contact (sensitizer), of ingestion, of inhalation (lung sensitizer).

CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC. Classified 2 (Some evidence.) by

NTP.

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available.

The substance is toxic to skin.

The substance may be toxic to kidneys, lungs, liver, upper respiratory tract.

Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at

least 15 minutes. Get medical attention if irritation occurs.

Skin Contact:

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated

clothing and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean

shoes before reuse. Get medical attention.

Serious Skin Contact: Not available.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

medical attention.

Serious Inhalation: Not available.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an

unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight

clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available.

Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions:

Flammable solid.

SMALL FIRE: Use DRY chemical powder.

LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet in order to prevent pressure

build-up, autoignition or explosion.

Special Remarks on Fire Hazards: Material in powder form, capable of creating a dust explosion. This material is flammable

in powder form only.

Special Remarks on Explosion Hazards:

Material in powder form, capable of creating a dust explosion.

Mixtures containing Potassium Perchlorate with Nickel & Titanium powders & infusorial earth can explode.

Adding 2 or 3 drops of approximately 90% peroxyformic acid to powdered nickel will result in explosion.

Powdered nickel reacts explosively upon contact with fused ammonium nitrate at temperatures below 200 deg. C.

Section 6: Accidental Release Measures

Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by

spreading water on the contaminated surface and dispose of according to local and regional authority

requirements.

Large Spill:

Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water

on the contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not

present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:

Keep locked up.. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear

suitable respiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Keep

away from incompatibles such as oxidizing agents, combustible materials, metals, acids.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below

recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to

airborne contaminants below the exposure limit.

Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.

Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used

to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist

BEFORE handling this product.

Exposure Limits:

TWA: 1 (mg/m3) from ACGIH (TLV) [United States] Inhalation Respirable.

TWA: 0.5 (mg/m3) [United Kingdom (UK)]

TWA: 1 (mg/m3) from OSHA (PEL) [United States] InhalationConsult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Metal solid. Lustrous solid.)

Odor: Odorless.

Taste: Not available.

Molecular Weight: 58.71 g/mole

Color: Silvery.

pH (1% soln/water): Not applicable.

Boiling Point: 2730°C (4946°F)

Melting Point: 1455°C (2651°F)

Critical Temperature: Not available.

Specific Gravity: Density: 8.908 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: Not available.

Solubility:

Insoluble in cold water, hot water.

Insoluble in Ammonia.

Soluble in dilute Nitric Acid.

Slightly soluble in Hydrochloric Acid, Sulfuric Acid.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, combustible materials, metals, acids.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:

Incompatible with strong acids, selenium, sulfur, wood and other combustibles, nickel nitrate, aluminum,

aluminum trichloride, ethylene, p-dioxan, hydrogen, methanol, non-metals, oxidants, sulfur compounds, aniline,

hydrogen sulfide, flammable solvents, hydrazine, and metal powders (especially zinc, aluminum, and magnesium),

ammonium nitrate, nitryl fluoride, bromine pentafluoride, potassium perchlorate + titanium powder + indusorial

earth.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals:

LD50: Not available.

LC50: Not available.

Chronic Effects on Humans:

CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC. Classified 2 (Some evidence.) by

NTP.

Causes damage to the following organs: skin.

May cause damage to the following organs: kidneys, lungs, liver, upper respiratory tract.

Other Toxic Effects on Humans:

Hazardous in case of inhalation.

Slightly hazardous in case of skin contact (irritant, sensitizer), of ingestion.

Special Remarks on Toxicity to Animals:

Lowest Published Lethal Dose/Conc:

LDL [Rat] - Route: Oral; Dose: 5000 mg/kg

LDL [Guinea Pig] - Route: Oral; Dose: 5000 mg/kg

Special Remarks on Chronic Effects on Humans: May cause cancer based on animal test data

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects:

Skin: Nickel dust and fume can irritate skin.

Eyes: Nickel dust and fume can irritate eyes.

Inhalation: Inhalation of dust or fume may cause respiratory tract irritation with non-productive cough,

hoarseness, sore throat, headache, vertigo, weakness, chest pain, followed by delayed effects, including

tachypnea, dyspnea, and ARDS. Death due to ARDS has been reported following inhalation of high

concentrations of respirable metallic nickel dust. Later effects may include pulmonary edema and fibrosis.

Ingestion: Metallic nickel is generally considered not to be acutely toxic if ingested. Ingestion may cause nausea,

vomiting, abdominal , and diarrhea. Nickel may damage the kidneys(proteinuria), and may affect liver function. It

may also affect behavior (somnolence), and cardiovascular system (increased cornary artery resistance,

decreased myocardial contractility, myocardial damage, regional or general arteriolar or venus dilation).

Chronic Potential Health Effects:

Skin: May cause skin allergy. Nickel and nickel compounds are among the most common sensitizers inducing

allergic contact dermatitis.

Inhalation: Chronic inhalation nickel dust or fume can cause chronic hypertrophic rhinitis, sinusitis, nasal polyps,

perforation of the nasal septum, chronic pulmonary irritation, fibrosis, pulmonary edema, pulmonary eosinophilia,

Pneumoconiosis, allergies (asthma-like allergy), and cancer of the nasal sinus cavities, lungs, and possibly other

organs. Future exposures can cause asthma attacks with shortness of breath, wheezing, cough, and/or chest

tightness. Chronic inhalation of nickel dust or fume may also affect the liver (impaired liver function tests), and

blood (changes in red blood cell count).

Ingestion: Prolonged or repeated ingestion of nickel can be a source chronic urticaria and other signs of allergy.

Chronic ingestion of NIckel may also affect respiration and cause pneumoconiosis or fibrosis.

Note: In the general population, sensitization occurs from exposure to nickel-containing coins, jewelry, watches,

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may

arise.

Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in accordance with federal, state and local environmental

control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations:

California prop. 65: This product contains the following ingredients for which the State of California has found to

cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: Nickel

metal

California prop. 65: This product contains the following ingredients for which the State of California has found to

cause cancer which would require a warning under the statute: Nickel metal

Connecticut hazardous material survey.: Nickel metal

Illinois toxic substances disclosure to employee act: Nickel metal

Illinois chemical safety act: Nickel metal

New York release reporting list: Nickel metal

Rhode Island RTK hazardous substances: Nickel metal

Pennsylvania RTK: Nickel metal

Michigan critical material: Nickel metal

Massachusetts RTK: Nickel metal

Massachusetts spill list: Nickel metal

New Jersey: Nickel metal

New Jersey spill list: Nickel metal

Louisiana spill reporting: Nickel metal

California Director's List of Hazardous Substances: Nickel metal

TSCA 8(b) inventory: Nickel metal

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

DSCL (EEC):

R40- Possible risks of irreversible

effects.

R43- May cause sensitization by skin

contact.

S22- Do not breathe dust.

S36- Wear suitable protective clothing.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 0

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves.

Lab coat.

Dust respirator. Be sure to use an

approved/certified respirator or

equivalent. Wear appropriate respirator

when ventilation is inadequate.

Safety glasses.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/10/2005 08:42 PM

Last Updated: 11/06/2008 12:00 PM