Nickel Aluminium Alloy Powder MSDS
Section 1: Chemical Product and Company Identification
Product Name: Nickel Aluminium Alloy Powder
Powder, Al-Ni 50/50
Catalog Codes: SLA1369
CAS#: 12635-27-7
RTECS: Not applicable.
TSCA: TSCA 8(b) inventory: Aluminum; Nickel metal
CI#: Not applicable.
Synonym:
Chemical Name: Not applicable.
Chemical Formula: Not applicable.
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Aluminum 7429-90-5 45-50
Nickel metal 7440-02-0 45-50
Toxicological Data on Ingredients: Aluminum LD50: Not available. LC50: Not available. Nickel metal LD50: Not available.
LC50: Not available.
Section 3: Hazards Identification
Potential Acute Health Effects:
Hazardous in case of skin contact (sensitizer), of inhalation. Slightly hazardous in case of skin contact (irritant), of eye contact
(irritant), of ingestion.
Potential Chronic Health Effects:
Slightly hazardous in case of skin contact (sensitizer), of ingestion, of inhalation (lung sensitizer). CARCINOGENIC
EFFECTS: Classified 2B (Possible for human.) by IARC [Nickel metal]. Classified 2 (Some evidence.) by NTP [Nickel metal].
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not
available. The substance is toxic to lungs, skin. The substance may be toxic to kidneys, liver. Repeated or prolonged exposure
to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15
minutes. Get medical attention if irritation occurs.
Skin Contact:
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing
and shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get
medical attention.
Serious Skin Contact:
Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical
attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If
breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical
attention.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious
person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,
tie, belt or waistband.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Flammable.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: Some metallic oxides.
Fire Hazards in Presence of Various Substances:
Highly flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks, of oxidizing
materials, of reducing materials, of combustible materials, of organic materials, of metals, of acids, of alkalis, of moisture.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in
presence of static discharge: Not available.
Fire Fighting Media and Instructions:
Flammable solid. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool containing vessels
with water jet in order to prevent pressure build-up, autoignition or explosion.
Special Remarks on Fire Hazards: MAY CATCH FIRE IF EXPOSED TO AIR.
Special Remarks on Explosion Hazards:
Material in powder form, capable of creating a dust explosion. Mixtures containing Potassium Perchlorate with Nickel &
Titanium powders & infusorial earth can explode. Adding 2 or 3 drops of approximately 90% peroxyformic acid to powdered
nickel will result in explosion. Powdered nickel reacts explosively upon contact with fused ammonium nitrate at temperatures
below 200 deg. C. (Nickel metal)
Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Flammable solid that, in contact with water, emits flammable gases. Stop leak if without risk. Do not get water inside container.
Do not touch spilled material. Cover with dry earth, sand or other non-combustible material. Prevent entry into sewers,
basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the
product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.
Section 7: Handling and Storage
Precautions:
Keep locked up.. Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do
not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If
you feel unwell, seek medical attention and show the label when possible. Keep away from incompatibles such as oxidizing
agents, combustible materials, metals, acids, alkalis.
Storage:
Keep container tightly closed. Keep container in a cool, well-ventilated area. Keep from any possible contact with water. Do
not allow water to get into container because of violent reaction. Air Sensitive
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended
exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants
below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid
inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this
product.
Exposure Limits:
TWA: 10 (mg/m3) from ACGIH (TLV) [United States] Inhalation TWA: 15 (mg/m3) from OSHA (PEL) [United States] Inhalation
Total. TWA: 10 (mg/m3) from NIOSH [United States] Inhalation Total. TWA: 5 (mg/m3) from NIOSH [United States] Inhalation
Respirable. TWA: 5 from OSHA (PEL) [United States] Inhalation Respirable.3 Consult local authorities for acceptable
exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid.
Odor: Odorless.
Taste: Not available.
Molecular Weight: 85.68
Color: grey.
pH (1% soln/water): Not applicable.
Boiling Point: Not available.
Melting Point: 1350°C (2462°F)
Critical Temperature: Not available.
Specific Gravity: 3.46 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Is not dispersed in cold water, hot water.
Solubility:
Insoluble in cold water, hot water. Reacts slowly with water forming Hydrogen gas
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, contact with water, exposure to air
Incompatibility with various substances:
Reactive with oxidizing agents, combustible materials, metals, acids, alkalis. Slightly reactive to reactive with moisture. The
product reacts violently with water to emit flammable but non toxic gases.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Aluminum: Moisture sensitive. Aluminum reacts vigorously with Sodium Hydroxide. Aluminum is also incompatible with
strong oxdizers, acids, chromic anhydride, iodine, carbon disulfide, methyl chloride, and halogenated hydrocarbons, acid
chlorides, ammonium nitrate, ammonium persulfate, antimony, arsenic oxides, barium bromate, barium chlorate, barium
iodate, metal salts Nickel: Incompatible with strong acids, selenium, sulfur, wood and other combustibles, nickel nitrate,
aluminum, aluminum trichloride, ethylene, p-dioxan, hydrogen, methanol, non-metals, oxidants, sulfur compounds, aniline,
hydrogen sulfide, flammable solvents, hydrazine, and metal powders (especially zinc, aluminum, and magnesium), ammonium
nitrate, nitryl fluoride, bromine pentafluoride, potassium perchlorate + titanium powder + indusorial earth, phosphorus, fluorine,
dioxane + hydrogen, hydrazoic acid. Air sensitive.
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals:
LD50: Not available. LC50: Not available.
Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified 2B (Possible for human.) by IARC [Nickel metal]. Classified 2 (Some evidence.) by
NTP [Nickel metal]. Contains material which may cause damage to the following organs: kidneys, liver.
Other Toxic Effects on Humans:
Hazardous in case of skin contact (sensitizer), of inhalation. Slightly hazardous in case of skin contact (irritant), of ingestion.
Special Remarks on Toxicity to Animals:
Lowest Published Lethal Dose/Conc: LDL [Rat] - Route: Oral; Dose: 5000 mg/kg LDL [Guinea Pig] - Route: Oral; Dose: 5000
mg/kg (Nickel metal)
Special Remarks on Chronic Effects on Humans: May cause cancer based on animal test data (Nickel metal)
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects: Skin: It can cause skin irritation Eyes: It can cause eye irritation. Aluminum particles deposited
in the eye are generally innocous. Inhalation: Inhalation of dust or fume may cause respiratory tract irritation with nonproductive
cough, hoarseness, sore throat. Other symptoms may include headache, vertigo, weakness, chest pain, followed
by delayed effects, including tachypnea, dyspnea, and ARDS. Death due to ARDS has been reported following inhalation
of high concentrations of respirable metallic nickel dust. Later effects may include pulmonary edema and fibrosis. Heating
Aluminum can release Aluminum Oxide fumes and cause fume metal fever when inhaled. This is a flu-like illness with
symptoms of metallic taste, fever, chills, aches, chest tightness, and cough. Ingestion: Aluminum or Nickel are generally
considered not to be acutely toxic if ingested. Ingestion of Nickel
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.
Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental control regulations.
Section 14: Transport Information
DOT Classification: CLASS 4.2: Spontaneously combustible substance.
Identification: : Metal Catalyst, Dry, n.o.s(Aluminum-nickel alloy powder) UNNA: 2881 PG: III
Special Provisions for Transport: Not available.
Section 15: Other Regulatory Information
Federal and State Regulations:
California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,
birth defects or other reproductive harm, which would require a warning under the statute: Nickel metal California prop. 65:
This product contains the following ingredients for which the State of California has found to cause cancer which would
require a warning under the statute: Nickel metal Connecticut hazardous material survey.: Aluminum; Nickel metal Illinois
toxic substances disclosure to employee act: Aluminum; Nickel metal Illinois chemical safety act: Nickel metal New York
release reporting list: Nickel metal Rhode Island RTK hazardous substances: Aluminum; Nickel metal Pennsylvania RTK:
Aluminum; Nickel metal Minnesota: Aluminum Michigan critical material: Nickel metal Massachusetts RTK: Aluminum; Nickel
metal Massachusetts spill list: Nickel metal New Jersey: Aluminum; Nickel metal New Jersey spill list: Aluminum; Nickel metal
Louisiana spill reporting: Nickel metal TSCA 8(b) inventory: Aluminum; Nickel metal SARA 313 toxic chemical notification and
release reporting: Aluminum 47.5%; Nickel metal 47.5% CERCLA: Hazardous substances.: Nickel metal: 100 lbs. (45.36 kg);
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS B-6: Reactive and very flammable material. CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC):
R15- Contact with water liberates extremely flammable gases. R40- Possible risks of irreversible effects. R43- May cause
sensitization by skin contact. S22- Do not breathe dust. S36/37- Wear suitable protective clothing and gloves.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 3
Reactivity: 1
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 1
Specific hazard:
Protective Equipment:
Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator
when ventilation is inadequate. Safety glasses.
Section 16: Other Information
References: Not available.
Other Special Considerations: Not available.
Created: 10/09/2005 03:39 PM
Last Updated: 11/06/2008 12:00 PM