N-N-Propylamine For Synthesis  MSDS

Section 1: Chemical Product and Company Identification

Product Name: N-Propylamine For Synthesis

Catalog Codes: SLP4195

CAS#: 107-10-8

RTECS: UH9100000

TSCA: TSCA 8(b) inventory: No products were found.

CI#: Not available.

Synonym: 1-Aminopropane

Chemical Name: N-Propylamine For Synthesis

Chemical Formula: C3-H9-N

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

N-Propylamine For Synthesis  107-10-8 100

Toxicological Data on Ingredients: N-Propylamine For Synthesis : ORAL (LD50): Acute: 570 mg/kg [Rat]. VAPOR (LC50): Acute: 2310 ppm 4

hour(s) [Rat]. 731.2 ppm 4 hour(s) [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant, sensitizer), of eye contact (irritant, corrosive), of ingestion, of inhalation (lung

irritant, lung sensitizer). Severe over-exposure can result in death. Inflammation of the eye is characterized by redness,

watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Classified None. for human. TERATOGENIC EFFECTS:

Classified None. for human. DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female [SUSPECTED].

Classified Reproductive system/toxin/male, Development toxin [None.]. The substance is toxic to kidneys, lungs, heart.

Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to an highly toxic

material may produce general deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids

open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:

After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running

water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an

emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical

attention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If

breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may

be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or

corrosive. Seek immediate medical attention.

Ingestion:

Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that

the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,

tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: 317°C (602.6°F)

Flash Points: OPEN CUP: -37.26°C (-35.1°F).

Flammable Limits: LOWER: 2% UPPER: 10.4%

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances: Highly flammable in presence of open flames and sparks, of heat.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Explosive in presence of open flames and

sparks, of heat.

Fire Fighting Media and Instructions:

Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,

water spray or fog.

Special Remarks on Fire Hazards: Vapors are heavier than air and may travel to a source of ignition and flash back

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:

Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,

sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined

areas; dike if needed. Eliminate all ignition sources. Be careful that the product is not present at a concentration level above

TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:

Keep locked up Keep container dry. Keep away from heat. Keep away from sources of ignition. Ground all equipment

containing material. Do not ingest. Do not breathe gas/fumes/ vapour/spray. Never add water to this product In case of

insufficient ventilation, wear suitable respiratory equipment If ingested, seek medical advice immediately and show the

container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents, organic

materials.

Storage:

Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from

sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing

material. A refrigerated room would be preferable for materials with a flash point lower than 37.8°C (100°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective

threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid

inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this

product.

Exposure Limits:

Finland: STEL: 5 (ppm) SKIN Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Ammoniacal.

Taste: Not available.

Molecular Weight: 59.11 g/mole

Color: Colorless.

pH (1% soln/water): Not available.

Boiling Point: 48.5°C (119.3°F)

Melting Point: -83°C (-117.4°F)

Critical Temperature: 223.8°C (434.8°F)

Specific Gravity: Not available.

Vapor Pressure: 245 mm of Hg (@ 20°C)

Vapor Density: 2.04 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties:

Partially dispersed in hot water, diethyl ether. Very slightly dispersed in cold water. See solubility in diethyl ether, acetone.

Solubility:

Easily soluble in acetone. Partially soluble in hot water, diethyl ether. Very slightly soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Reactive with oxidizing agents, organic materials.

Corrosivity: Non-corrosive in presence of glass, of steel.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:

WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral

toxicity (LD50): 570 mg/kg [Rat]. Acute toxicity of the vapor (LC50): 731.2 ppm 4 hour(s) [Mouse].

Chronic Effects on Humans:

MUTAGENIC EFFECTS: Classified None. for human. TERATOGENIC EFFECTS: Classified None. for human.

DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female [SUSPECTED]. Classified Reproductive system/

toxin/male, Development toxin [None.]. The substance is toxic to kidneys, lungs, heart.

Other Toxic Effects on Humans:

Very hazardous in case of skin contact (irritant, sensitizer), of eye contact (corrosive), of ingestion, of inhalation (lung irritant,

lung sensitizer).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term

degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Class 3: Flammable liquid.

Identification: : N-Propylamine For Synthesis  : UN1277 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

Pennsylvania RTK: N-Propylamine For Synthesis  Florida: N-Propylamine For Synthesis  Massachusetts spill list: N-Propylamine For Synthesis  New Jersey: N-Propylamine For Synthesis  TSCA

8(b) inventory: No products were found. TSCA 4(a) proposed test rules: N-Propylamine For Synthesis  TSCA 8(d) H and S data reporting:

N-Propylamine For Synthesis : Mar 7, 1986 CERCLA: Hazardous substances.: N-Propylamine For Synthesis

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):

CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-1A: Material causing immediate and

serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

DSCL (EEC):

R11- Highly flammable. R20/21- Harmful by inhalation and in contact with skin. R36/37/38- Irritating to eyes, respiratory

system and skin.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 3

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 3

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator

when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 06:13 PM

Last Updated: 11/06/2008 12:00 PM