Papanicolaous Solution 3b MSDS

Section 1: Chemical Product and Company Identification

Product Name: Papanicolaous Solution 3b

Catalog Codes: SLP3862

CAS#: Mixture.

RTECS: Not applicable.

TSCA: TSCA 8(b) inventory: Ethyl alcohol 200 Proof;

Methyl alcohol; Orange G; Phosphotungstic acid; Water

CI#: Not applicable.

Synonym:

Chemical Name: Not applicable.

Chemical Formula: Not applicable.

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Ethyl alcohol 200 Proof 64-17-5 83.8

Methyl alcohol 67-56-1 4.2

Orange G 1936-15-8 0.35

Phosphotungstic acid 12501-23-4 0.015

Water 7732-18-5 11.6

Toxicological Data on Ingredients: Ethyl alcohol 200 Proof: ORAL (LD50): Acute: 7060 mg/kg [Rat.]. VAPOR (LC50): Acute:

8000 ppm 4 hour(s) [Rat.]. Methyl alcohol: ORAL (LD50): Acute: 5628 mg/kg [Rat.]. DERMAL (LD50): Acute: 15800 mg/kg

[Rabbit.]. VAPOR (LC50): Acute: 64000 ppm 4 hour(s) [Rat.].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of skin contact (irritant). Hazardous in case of eye contact (irritant). Slightly hazardous in case of

ingestion, of inhalation. Non-corrosive for skin. Non-sensitizer for skin.

Potential Chronic Health Effects:

Non-corrosive for skin. Non-sensitizer for skin. Non-permeator by skin. CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: PROVEN

 [Ethyl alcohol 200 Proof] The substance is toxic to the reproductive system, the nervous system. Repeated or prolonged

exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids

open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:

After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running

water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.

Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before

reusing.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical

attention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If

breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may

be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or

corrosive. Seek medical attention.

Ingestion:

Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that

the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,

tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Flammable.

Auto-Ignition Temperature: The lowest known value is 422°C (791.6°F) (Ethyl alcohol 200 Proof).

Flash Points: The lowest known value is CLOSED CUP: 12°C (53.6°F). (Methyl alcohol)

Flammable Limits: The greatest known range is LOWER: 6% UPPER: 36.5% (Methyl alcohol)

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), sulfur oxides (SO2,

SO3...).

Fire Hazards in Presence of Various Substances:

Flammable in presence of open flames and sparks, of heat, of combustible materials. Slightly flammable to flammable in

presence of oxidizing materials.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in

presence of static discharge: Not available.

Fire Fighting Media and Instructions:

Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use alcohol foam,

water spray or fog.

Special Remarks on Fire Hazards:

Containers should be grounded. CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME Vapor may travel considerable

distance to source of ignition and flash back. (Ethyl alcohol 200 Proof)

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:

Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.

Large Spill:

Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth,

sand or other non-combustible material. Do not touch spilled material. Prevent entry into sewers, basements or confined

areas; dike if needed. Eliminate all ignition sources. Be careful that the product is not present at a concentration level above

TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not

breathe gas/fumes/ vapour/spray. Wear suitable protective clothing If ingested, seek medical advice immediately and show the

container or the label. Avoid contact with skin and eyes Keep away from incompatibles such as oxidizing agents.

Storage:

Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from

sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing

material. A refrigerated room would be preferable for materials with a flash point lower than 37.8°C (100°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective

threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid

inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this

product.

Exposure Limits:

Ethyl alcohol 200 Proof TWA: 1000 (ppm) from OSHA (PEL) TWA: 1900 (mg/m3) from OSHA Methyl alcohol TWA: 200

STEL: 250 (ppm) from ACGIH (TLV) [1995] TWA: 262 STEL: 328 (mg/m3) from ACGIH [1995] Consult local authorities for

acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Not available.

Taste: Not available.

Molecular Weight: Not applicable.

Color: Not available.

pH (1% soln/water): Neutral.

Boiling Point: The lowest known value is 64.5°C (148.1°F) (Methyl alcohol). Weighted average: 80.42°C (176.8°F)

Melting Point: May start to solidify at -97.8°C (-144°F) based on data for: Methyl alcohol. Weighted average: -113.32°C

(-172°F)

Critical Temperature: Not available.

Specific Gravity: Weighted average: 0.81 (Water = 1)

Vapor Pressure:

The highest known value is 97.68 mm of Hg (@ 20°C) (Methyl alcohol). Weighted average: 42.33 mm of Hg (@ 20°C)

Vapor Density: The highest known value is 1.59 (Air = 1) (Ethyl alcohol 200 Proof). Weighted average: 1.46 (Air = 1)

Volatility: Not available.

Odor Threshold: The highest known value is 160 ppm (Methyl alcohol)

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties:

Is not dispersed in methanol, diethyl ether. See solubility in water, methanol, diethyl ether.

Solubility: Easily soluble in cold water, hot water, methanol, diethyl ether.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Reactive with oxidizing agents.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:

WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral

toxicity (LD50): 7926 mg/kg (Rat.) (Calculated value for the mixture). Acute dermal toxicity (LD50): 15800 mg/kg [Rabbit.].

(Methyl alcohol). Acute toxicity of the vapor (LC50): 9487 ppm 4 hour(s) (Rat.) (Calculated value for the mixture).

Chronic Effects on Humans:

DEVELOPMENTAL TOXICITY: PROVEN [Ethyl alcohol 200 Proof] The substance is toxic to the reproductive system, the

nervous system.

Other Toxic Effects on Humans:

Very hazardous in case of skin contact (irritant). Slightly hazardous in case of ingestion, of inhalation. Non-corrosive for skin.

Non-sensitizer for skin.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans:

0040 Passes through the placental barrier. May be fatal or cause blindness if swallowed. (Methyl alcohol)

Special Remarks on other Toxic Effects on Humans: Moderately toxic and narcotic in high concentrations. Experimentaly

tumorigen. (Ethyl alcohol 200 Proof)

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Class 3: Flammable liquid.

Identification: : Denatured alcohol, solution (Ethyl alcohol 200 Proof) : UN1987 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer,

birth defects or other reproductive harm, which would require a warning under the statute: Ethyl alcohol 200 Proof California

prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects

which would require a warning under the statute: Ethyl alcohol 200 Proof California prop. 65: This product contains the

following ingredients for which the State of California has found to cause cancer which would require a warning under the

statute: Ethyl alcohol 200 Proof Pennsylvania RTK: Ethyl alcohol 200 Proof; Methyl alcohol Massachusetts RTK: Ethyl alcohol

200 Proof; Methyl alcohol TSCA 8(b) inventory: Ethyl alcohol 200 Proof; Methyl alcohol; Orange G; Phosphotungstic acid;

Water SARA 313 toxic chemical notification and release reporting: Methyl alcohol CERCLA: Hazardous substances.: Methyl

alcohol;

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):

CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). CLASS D-2A: Material causing other toxic effects

(VERY TOXIC).

DSCL (EEC):

R11- Highly flammable. R36/38- Irritating to eyes and skin.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 3

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 3

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator

when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/11/2005 01:38 PM

Last Updated: 11/06/2008 12:00 PM