P-Toluidine For Synthesis MSDS

Section 1: Chemical Product and Company Identification

Product Name: P-Toluidine For Synthesis

Catalog Codes: SLD1888

CAS#: 106-49-0

RTECS: XU5803000

TSCA: TSCA 8(b) inventory: P-Toluidine For Synthesis

CI#: Not available.

Synonym: 4-Dimethylaminotoluene; Benzenamine,

N,N,-4-trimethyl-; N,N,4-Trimethylaniline;

Dimethyl-p-toluidine; p,N,N-Trimet;hylaniline; p-

(Dimethylamino)toluene

Chemical Name: P-Toluidine For Synthesis

Chemical Formula: C9-H13-N

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by

Weight

{N,N-}Dimethyl-p-toluidine 106-49-0 100

Toxicological Data on Ingredients: P-Toluidine For Synthesis : VAPOR (LC50): Acute: 1400 mg/m 4 hours [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of skin contact (irritant, permeator), of eye contact (irritant), of ingestion, of inhalation. Severe overexposure

can result in death.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available. Repeated exposure to a highly toxic material may produce general deterioration

of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15

minutes. Get medical attention.

Skin Contact:

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated

clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical

attention.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical

attention immediately.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband.

WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is

toxic, infectious or corrosive. Seek immediate medical attention.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious

person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,

tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Combustible.

Auto-Ignition Temperature: Not available.

Flash Points: CLOSED CUP: 83°C (181.4°F).

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:

Flammable in presence of open flames and sparks, of heat. Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in

presence of static discharge: Not available.

Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Absorb with an inert material and put the spilled material in an appropriate waste disposal.

Large Spill:

Combustible material. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk.

Section 7: Handling and Storage

Precautions:

Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not ingest. Do not

breathe gas/fumes/ vapor/spray. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory

equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and

eyes. Keep away from incompatibles such as oxidizing agents.

Storage:

Keep container in a cool, well-ventilated area. Keep container tightly closed and sealed until ready for use. Avoid all possible

sources of ignition (spark or flame).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective

threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:

Splash goggles. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid

inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this

product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Liquid.

Odor: Not available.

Taste: Not available.

Molecular Weight: 135.21 g/mole

Color: Clear Colorless to light yellow.

pH (1% soln/water): Not applicable.

Boiling Point: 211°C (411.8°F)

Melting Point: Not available.

Critical Temperature: Not available.

Specific Gravity: 0.937(Water = 1)

Vapor Pressure: Not available.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: Not available.

Solubility: Insoluble in cold water, hot water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Heat, ignition sources, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents.

Corrosivity: Not available.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact.

Toxicity to Animals:

WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute toxicity

of the vapor (LC50): 1400 mg/m 4 hours [Rat]. 3

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, permeator), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: May affect genetic material (mutagenic)

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects: Skin: May cause skin irritation. May be harmful if absorbed through skin. Eyes: May cause eye

irritation. Inhalation: May cause respiratory tract irritation. May affect respiration (dyspnea, respiratory stimulation). Harmful if

inhaled. Ingestion: May cause gastrointestinal tract irritation with nausea, vomiting, and diarrhea. Harmful if swallowed. The

toxicological properties of this substance have not been fully investigated. Chronic Potential Health Effects: There is a danger

of cumulative effects.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: CLASS 6.1: Poisonous material.

Identification: : Toxic Liquid, Organic, n.o.s. (P-Toluidine For Synthesis ) UNNA: 2810 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: P-Toluidine For Synthesis

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on the

European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): Not available

DSCL (EEC):

R23/24/25- Toxic by inhalation, in contact with skin and if swallowed. R33- Danger of cumulative effects. R52/53- Harmful

to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S28- After contact with skin, wash

immediately with plenty of [***] S36/37- Wear suitable protective clothing and gloves. S45- In case of accident or if you feel

unwell, seek medical advice immediately (show the label where possible). S61- Avoid release to the environment. Refer to

special instructions/Safety data sheets.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 2

Reactivity: 0

Personal Protection: h

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 2

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves. Lab coat. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 05:13 PM

Last Updated: 11/06/2008 12:00 PM