MSDS Number: P7896 * * * * * Effective Date: 11/21/08 * * * * * Supercedes: 02/16/06 PYROCATECHOL


PYROCATECHOL


1. Product Identification

Synonyms: Catechol; 1,2-benzenediol; 1,2-dihydroxy benzene
CAS No.: 120-80-9
Molecular Weight: 110.11
Chemical Formula: C6H6O2
Product Codes:
J.T. Baker: U672
Mallinckrodt: 1724

2. Composition/Information on Ingredients


 
  Ingredient                                CAS No         Percent        Hazardous                                  
  ---------------------------------------   ------------   ------------   ---------   
 
  Catechol                                  120-80-9         90 - 100%       Yes                                                                    
 

3. Hazards Identification

Emergency Overview
--------------------------
DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CORROSIVE. CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT. AFFECTS EYES, SKIN, RESPIRATORY TRACT AND CENTRAL NERVOUS SYSTEM. EXPOSURE MAY PRODUCE LIVER, KIDNEY, AND NEUROLOGICAL DISORDERS. MAY CAUSE ALLERGIC SKIN REACTION.

SAF-T-DATA(tm) Ratings (Provided here for your convenience)
-----------------------------------------------------------------------------------------------------------
Health Rating: 3 - Severe (Life)
Flammability Rating: 1 - Slight
Reactivity Rating: 1 - Slight
Contact Rating: 3 - Severe (Corrosive)
Lab Protective Equip: GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
Storage Color Code: White (Corrosive)
-----------------------------------------------------------------------------------------------------------

Potential Health Effects
----------------------------------

Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing, shortness of breath. Breathing vapor or dust results in digestive disturbances (vomiting, difficulty in swallowing, diarrhea, loss of appetite). Systemic poisoning may occur with symptoms similar to those of ingestion.
Ingestion:
Poison. Symptoms may include burning pain in mouth and throat, abdominal pain, headache, dizziness, muscular weakness, irregular breathing, coma, and possibly death. May interfere with blood's capability to carry oxygen (methemoglobinemia), as evidenced by bluish color to skin and lips. With catechol exposure, convulsions are more marked than with phenol exposure, and blood dyscrasias (imbalance of components of the blood) have been noted.
Skin Contact:
Corrosive. May be absorbed through the skin with systemic poisoning effects to follow. Discoloration and severe burns may occur. May cause allergic skin reactions.
Eye Contact:
Corrosive. Redness, pain, blurred vision may occur. May cause severe damage and blindness.
Chronic Exposure:
Repeated exposure may cause symptoms described for acute poisoning as well as liver damage.
Aggravation of Pre-existing Conditions:
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance.

4. First Aid Measures

Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.

5. Fire Fighting Measures

Fire:
Flash point: 127.2C (261F) CC
Flammable limits in air % by volume:
lel: 1.4
As with most organic solids, fire is possible at elevated temperatures or by contact with an ignition source.
Explosion:
Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. Sealed containers may rupture when heated.
Fire Extinguishing Media:
Water spray, dry chemical, alcohol foam, or carbon dioxide.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.



7. Handling and Storage

Keep in a tightly closed container. Store in a cool, dry, ventilated area away from sources of heat or ignition. Protect against physical damage. Store separately from reactive or combustible materials, and out of direct sunlight. Storage and use should be in No Smoking Areas. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits:
Catechol:
- ACGIH Threshold Limit Value (TLV):
5 ppm (TWA) skin, A3 animal carcinogen.
- NIOSH Recommended Exposure Limits (RELs):
5 ppm (TWA) skin.
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded and engineering controls are not feasible, a half-face respirator with an organic vapor cartridge and particulate filter (NIOSH type N95 or better filter) may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece respirator with an organic vapor cartridge and particulate filter (NIOSH N 100 filter) may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. If oil particles (e.g. lubricants, cutting fluids, glycerine, etc.) are present, use a NIOSH type R or P particulate filter. For emergencies or instances where the exposure levels are not known, use a full-face piece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Where respirators are required, you must have a written program covering the basic requirements in the OSHA respirator standard. These include training, fit testing, medical approval, cleaning, maintenance, cartridge change schedules, etc. See 29CFR1910.134 for details.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.

9. Physical and Chemical Properties

Appearance:
Colorless crystals.
Odor:
Phenolic odor.
Solubility:
Soluble in 2-3 parts water.
Specific Gravity:
1.344
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
245C (473F)
Melting Point:
104 - 106C (219 - 223F)
Vapor Density (Air=1):
3.79
Vapor Pressure (mm Hg):
10 @ 118.3C (244F)
Evaporation Rate (BuAc=1):
No information found.

10. Stability and Reactivity

Stability:
Stable under ordinary conditions of use and storage. Light sensitive. Discolors on exposure to air or light.
Hazardous Decomposition Products:
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Acid chlorides, acid anhydrides, bases, oxidizing agents.
Conditions to Avoid:
Heat, flames, ignition sources and incompatibles.

11. Toxicological Information


Oral rat LD50: 260 mg/kg; skin rabbit LD50: 800 mg/kg; Investigated as a tumorigen, mutagen, reproductive effector.
 
  --------\Cancer Lists\------------------------------------------------------
                                         ---NTP Carcinogen---
  Ingredient                             Known    Anticipated    IARC Category
  ------------------------------------   -----    -----------    -------------
  Catechol (120-80-9)                     No          No             2B

12. Ecological Information

Environmental Fate:
When released into the soil, this material may biodegrade to a moderate extent. When released into the soil, this material is not expected to evaporate significantly. When released into water, this material may biodegrade to a moderate extent. When released into water, this material is not expected to evaporate significantly. This material is not expected to significantly bioaccumulate. When released into the air, this material is expected to be readily degraded by reaction with photochemically produced hydroxyl radicals.
Environmental Toxicity:
The LC50/96-hour values for fish are between 1 and 10 mg/l.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.

14. Transport Information

Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (PYROCATECHOL)
Hazard Class: 6.1, 8
UN/NA: UN2928
Packing Group: II
Information reported for product/size: 500G

International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (PYROCATECHOL)
Hazard Class: 6.1, 8
UN/NA: UN2928
Packing Group: II
Information reported for product/size: 500G

International (Air, I.C.A.O.)
-----------------------------
Proper Shipping Name: TOXIC SOLID, CORROSIVE, ORGANIC, N.O.S. (PYROCATECHOL)
Hazard Class: 6.1, 8
UN/NA: UN2928
Packing Group: II
Information reported for product/size: 500G

15. Regulatory Information

 
  --------\Chemical Inventory Status - Part 1\---------------------------------
  Ingredient                                       TSCA  EC   Japan  Australia
  -----------------------------------------------  ----  ---  -----  ---------
  Catechol (120-80-9)                               Yes  Yes   Yes      Yes                                      
 
  --------\Chemical Inventory Status - Part 2\---------------------------------
                                                          --Canada--
  Ingredient                                       Korea  DSL   NDSL  Phil.
  -----------------------------------------------  -----  ---   ----  -----
  Catechol (120-80-9)                               Yes   Yes   No     Yes
 
  --------\Federal, State & International Regulations - Part 1\----------------
                                             -SARA 302-    ------SARA 313------
  Ingredient                                 RQ    TPQ     List  Chemical Catg.
  -----------------------------------------  ---   -----   ----  --------------
  Catechol (120-80-9)                        No    No      Yes        No
 
  --------\Federal, State & International Regulations - Part 2\----------------
                                                        -RCRA-    -TSCA-
  Ingredient                                 CERCLA     261.33     8(d) 
  -----------------------------------------  ------     ------    ------
  Catechol (120-80-9)                        100        No         Yes                                                                 
 
 
Chemical Weapons Convention:  No     TSCA 12(b):  Yes    CDTA:  No
SARA 311/312:  Acute: Yes      Chronic: Yes  Fire: No  Pressure: No
Reactivity: No          (Pure / Solid) 
WARNING:
THIS PRODUCT CONTAINS A CHEMICAL(S) KNOWN TO THE STATE OF CALIFORNIA TO CAUSE CANCER.

Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

16. Other Information

NFPA Ratings: Health: 3 Flammability: 1 Reactivity: 0
Label Hazard Warning:
DANGER! MAY BE FATAL IF SWALLOWED, INHALED OR ABSORBED THROUGH SKIN. CORROSIVE. CAUSES SEVERE BURNS TO EVERY AREA OF CONTACT. AFFECTS EYES, SKIN, RESPIRATORY TRACT AND CENTRAL NERVOUS SYSTEM. EXPOSURE MAY PRODUCE LIVER, KIDNEY, AND NEUROLOGICAL DISORDERS. MAY CAUSE ALLERGIC SKIN REACTION.
Label Precautions:
Do not breathe dust or vapor.
Do not get in eyes, on skin, or on clothing.
Keep container closed.
Use only with adequate ventilation.
Wash thoroughly after handling.
Label First Aid:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. In all cases get medical attention immediately.
Product Use:
Laboratory Reagent.
Revision Information:
MSDS Section(s) changed since last revision of document include: 3.
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Prepared by: Environmental Health & Safety
Phone Number: (314) 654-1600 (U.S.A.)