Sodium (+) Ascorbate MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sodium (+) Ascorbate

Catalog Codes: SLS2953, SLS4375, SLS2158

CAS#: 134-03-2

RTECS: CI7671000

TSCA: TSCA 8(b) inventory: Sodium (+) Ascorbate

CI#: Not available.

Synonym: Ascorbicin, Ascorbin, Cebitate, Natrascorb;

Sodium L-Ascorbate; Vitamin C Sodium

Chemical Name: L-Ascorbic Acid, monsodium salt

Chemical Formula: C6H7NaO6

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sodium (+) Ascorbate 134-03-2 100

Toxicological Data on Ingredients: Sodium (+) Ascorbate: ORAL (LD50): Acute: 17531 mg/kg [Mouse]. 16300 mg/kg [Rat].

Section 3: Hazards Identification

Potential Acute Health Effects:

Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of

inhalation.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP, None. by OSHA.

MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.

TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available.

The substance may be toxic to kidneys, gastrointestinal tract, upper respiratory tract.

Repeated or prolonged exposure to the substance can produce target organs damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at

least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.

Skin Contact:

Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.

Cold water may be used.

Serious Skin Contact: Not available.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

medical attention.

Serious Inhalation: Not available.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an

unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if

symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2). Some metallic oxides.

Fire Hazards in Presence of Various Substances:

Slightly flammable to flammable in presence of heat.

Non-flammable in presence of shocks.

Explosion Hazards in Presence of Various Substances:

Slightly explosive in presence of open flames and sparks.

Non-explosive in presence of shocks.

Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder.

LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: As with most organic solids, fire is possible at elevated temperatures

Special Remarks on Explosion Hazards:

Fine dust dispersed in air in sufficient concentrations, and in the presences of an ignition source is a potential dust

explosion hazard.

Section 6: Accidental Release Measures

Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by

spreading water on the contaminated surface and dispose of according to local and regional authority

requirements.

Large Spill:

Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water

on the contaminated surface and allow to evacuate through the sanitary system.

Section 7: Handling and Storage

Precautions:

Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk,

evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not

breathe dust. Wear suitable protective clothing. If ingested, seek medical advice immediately and show the

container or the label. Keep away from incompatibles such as oxidizing agents, reducing agents, acids, alkalis.

Storage:

Keep container tightly closed. Keep container in a cool, well-ventilated area. Sensitive to light. Store in

light-resistant containers.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below

recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to

airborne contaminants below the exposure limit.

Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.

Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used

to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist

BEFORE handling this product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Granular solid. Crystals solid.)

Odor: Odorless.

Taste: Not available.

Molecular Weight: 198.11 g/mole

Color: White. White to yellowish.

pH (1% soln/water): Not available.

Boiling Point: Not available.

Melting Point: Decomposition temperature: 200°C (392°F) - 218 C

Critical Temperature: Not available.

Specific Gravity: 1.66 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility:

Easily soluble in cold water.

Insoluble in diethyl ether.

Insoluble in chloroform and alcohol.

Solubility in water: 62 g/100 ml @ 25 deg. C and 78 g/100 ml @ 75 deg. C

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Excess heat, light, incompatible materials

Incompatibility with various substances: Reactive with oxidizing agents, reducing agents, acids, alkalis.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity:

Sensitive to light. It gradually darkens on exposure to light.

On prolonged strorage, a yellow discoloration may occur through slow decompostion.

Incompatible with compounds rich in oxygen

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 16300 mg/kg [Rat].

Chronic Effects on Humans:

CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP, None. by OSHA.

MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.

May cause damage to the following organs: kidneys, gastrointestinal tract, upper respiratory tract.

Other Toxic Effects on Humans:

Hazardous in case of ingestion.

Slightly hazardous in case of skin contact (irritant), of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans:

May affect genetic material (mutagenic) based on animal test data. No human data found. (Registry of Toxic

Effects of Chemicals)

May cause cancer based on animal test data. No human data found. (Registry of Toxic Effects of Chemicals)

Special Remarks on other Toxic Effects on Humans:

Acute Potential Health Effects:

Skin: May cause skin irritation.

Eyes: May cause eye irritation.

Inhalation: May cause upper respiratory tract and mucous membrane irritation.

Ingestion: May cause gastrointestinal tract effects. Symptoms may include nausea, vomiting, diarrhea,

constipation, cramps, heartburn, loss of appetite. Other symptoms may include headache, insomnia, sleepiness,

fatigue, flushing

Chronic Potential Health Effects:

Ingestion: May cause kidney or bladder stones which are caused by acidification of urine and precipitation of

cystine or oxalate.

Conditions aggravated by exposure: Hemachromatosis, thalassemia, sideroblastic or sickle cell anemial.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term

degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Waste must be disposed of in accordance with federal, state and local environmental

control regulations.

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Sodium ascorbate

Other Regulations:

OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):

R40- Possible risks of irreversible

effects.

S2- Keep out of the reach of children.

S36/37- Wear suitable protective clothing and

gloves.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves.

Lab coat.

Dust respirator. Be sure to use an

approved/certified respirator or

equivalent.

Safety glasses.

Section 16: Other Information

References:

-Manufacturer's Material Safety Data Sheet.

Registry of Toxic Effects of Chemicals (RTECS)

Other Special Considerations: Not available.

Created: 10/09/2005 06:29 PM

Last Updated: 11/06/2008 12:00 PM