Aluminium Fluoborate (aluminium borofluoride) MSDS

Section 1: Chemical Product and Company Identification

Product Name: Aluminium Fluoborate (aluminium borofluoride)

Catalog Codes: SLA4207

CAS#: 13826-83-0

RTECS: BQ6100000

TSCA: TSCA 8(b) inventory: Aluminium Fluoborate (aluminium borofluoride)

CI#: Not available.

Synonym: Ammonium tetrafluoroborate

Chemical Name: Not available.

Chemical Formula: NH4BF4

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Aluminium Fluoborate (aluminium borofluoride) 13826-83-0 100

Toxicological Data on Ingredients: Ammonium fluoborate LD50: Not available. LC50: Not available.

Section 3: Hazards Identification

Potential Acute Health Effects:

Extremely hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Corrosive to eyes and skin. The amount of tissue damage depends on length of contact. Eye contact can result

in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will

produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing.

Severe over-exposure can produce lung damage, choking, unconsciousness or death. Inflammation of the eye is

characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening,

or, occasionally, blistering.

Potential Chronic Health Effects:

Extremely hazardous in case of eye contact (irritant), of ingestion, of inhalation.

Very hazardous in case of skin contact (irritant).

CARCINOGENIC EFFECTS: Not available.

MUTAGENIC EFFECTS: Not available.

TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available.

Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can

produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of

respiratory irritation or lung damage. Repeated or prolonged inhalation of dust may lead to chronic respiratory

irritation.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at

least 15 minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:

In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated

clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before

reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical

attention.

Inhalation:

If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get

medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or

waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth

resuscitation. WARNING: It may be hazardous to the person providing aid to give mouth-to-mouth resuscitation

when the inhaled material is toxic, infectious or corrosive. Seek immediate medical attention.

Ingestion:

Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an

unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight

clothing such as a collar, tie, belt or waistband.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available.

Risks of explosion of the product in presence of static discharge: Not available.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

Large Spill:

Corrosive solid.

Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to

reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on

disposal.

Section 7: Handling and Storage

Precautions:

Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear

suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label.

Avoid contact with skin and eyes. May corrode glass. Store in an appropriate container.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below

recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to

airborne contaminants below the exposure limit.

Personal Protection:

Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or

equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus

should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a

specialist BEFORE handling this product.

Exposure Limits: Not available.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystalline solid.)

Odor: Not available.

Taste: Not available.

Molecular Weight: 104.84 g/mole

Color: Colorless to light yellow.

pH (1% soln/water): Not available.

Boiling Point: Decomposes.

Melting Point: 230°C (446°F)

Critical Temperature: Not available.

Specific Gravity: 1.871 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water, methanol.

Solubility:

Soluble in cold water.

Partially soluble in methanol.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Not available.

Corrosivity: Corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Eye contact. Inhalation. Ingestion.

Toxicity to Animals:

LD50: Not available.

LC50: Not available.

Chronic Effects on Humans: Not available.

Other Toxic Effects on Humans: Extremely hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may

arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Ammonium Fluoborate UNNA: UN1759 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

Pennsylvania RTK: Ammonium fluoborate

Massachusetts RTK: Ammonium fluoborate

TSCA 8(b) inventory: Ammonium fluoborate

CERCLA: Hazardous substances.: Ammonium fluoborate

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada): CLASS E: Corrosive solid.

DSCL (EEC):

R38- Irritating to skin.

R41- Risk of serious damage to eyes.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 0

Personal Protection: j

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves.

Synthetic apron.

Vapor and dust respirator. Be sure to

use an approved/certified respirator or

equivalent. Wear appropriate respirator

when ventilation is inadequate.

Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 03:55 PM

Last Updated: 11/06/2008 12:00 PM