Ammonium Tungstate MSDS
Section 1: Chemical Product and Company Identification
Product Name: Ammonium Tungstate
Catalog Codes: SLA1090
CAS#: 11120-25-5
RTECS: Not available.
TSCA: TSCA 8(b) inventory: Ammonium Tungstate
CI#: Not available.
Synonym: Tungstic Acid, hexaammonium salt; Ammonium
Tungstate (Meta); Ammonium Metatungstate, hydrate
Chemical Name: Ammonium Tungstate
Chemical Formula: (NH4)6H2W12O40.xH2O
Section 2: Composition and Information on Ingredients
Composition:
Name CAS # % by Weight
Ammonium Tungstate 11120-25-5 100
Toxicological Data on Ingredients: Ammonium Tungstate LD50: Not available. LC50: Not available.
Section 3: Hazards Identification
Potential Acute Health Effects:
Hazardous in case of ingestion. Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of
inhalation.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Not available.
The substance may be toxic to kidneys.
Repeated or prolonged exposure to the substance can produce target organs damage.
Section 4: First Aid Measures
Eye Contact:
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Cold water may be used. Get medical attention if irritation occurs.
Skin Contact:
Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops.
Cold water may be used.
Serious Skin Contact: Not available.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
medical attention.
Serious Inhalation: Not available.
Ingestion:
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an
unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight
clothing such as a collar, tie, belt or waistband.
Serious Ingestion: Not available.
Section 5: Fire and Explosion Data
Flammability of the Product: Non-flammable.
Auto-Ignition Temperature: Not applicable.
Flash Points: Not applicable.
Flammable Limits: Not applicable.
Products of Combustion: Not available.
Fire Hazards in Presence of Various Substances: Not applicable.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions: Not applicable.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
Section 6: Accidental Release Measures
Small Spill:
Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by
spreading water on the contaminated surface and dispose of according to local and regional authority
requirements.
Large Spill:
Isolate spill area and provide ventilation. Vacuum up spill using a HEPA air filter or use a shovel to pick up the
spilled material and place material in a closed container for proper disposal. Take care not to raise dust. Finish
cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Be
careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with
local authorities.
Section 7: Handling and Storage
Precautions: Do not breathe dust. Keep away from incompatibles such as oxidizing agents, alkalis.
Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.
Section 8: Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits:
TWA: 5 (mg/m3) from OSHA (PEL) [United States]
TWA: 1 (mg/m3) from ACGIH (TLV) [United States]
Consult local authorities for acceptable exposure limits.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid. (Crystalline powder. Powdered solid.)
Odor: Odorless.
Taste: Not available.
Molecular Weight: 2938.41 g/mole
Color: White.
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: 4 (Water = 1)
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: See solubility in water.
Solubility:
Partially soluble in cold water.
Insoluble in methanol, n-octanol.
Section 10: Stability and Reactivity Data
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Incompatible materials, dust generation
Incompatibility with various substances: Reactive with oxidizing agents, alkalis.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity:
Also incompatible with halogens.
Strong bases may release ammonia gas
Special Remarks on Corrosivity: Not available.
Polymerization: Will not occur.
Section 11: Toxicological Information
Routes of Entry: Inhalation. Ingestion.
Toxicity to Animals:
LD50: Not available.
LC50: Not available.
Chronic Effects on Humans: May cause damage to the following organs: kidneys.
Other Toxic Effects on Humans:
Hazardous in case of ingestion.
Slightly hazardous in case of skin contact (irritant), of inhalation.
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans:
Acute Potential Health Effects:
Skin: May cause mild irritation of the skin with redness, and itching.
Eyes: May cause mild irritation of the eyes with redness, itching, watering.
Inhalation: May cause irritation to th enose, mucous membranes and respiratory tract with sneezing, dry throat,
and coughing.
Ingestion: Tungstate compounds may cause changes in body weight and behavior.
Chronic Potential Health Effects:
Skin: Prolonged or repeated contact may cause dermatitis.
Ingestion: Prolonged or repeated ingestion of large doses may cause kidney damage
Section 12: Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation: The products of degradation are as toxic as the original product.
Special Remarks on the Products of Biodegradation: Not available.
Section 13: Disposal Considerations
Waste Disposal:
Waste must be disposed of in accordance with federal, state and local environmental
control regulations.
Section 14: Transport Information
DOT Classification: Not a DOT controlled material (United States).
Identification: Not applicable.
Special Provisions for Transport: Not applicable.
Section 15: Other Regulatory Information
Federal and State Regulations: TSCA 8(b) inventory: Ammonium metatungstate
Other Regulations:
OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other Classifications:
WHMIS (Canada): Not controlled under WHMIS (Canada).
DSCL (EEC):
This product is not classified according
to the EU regulations.
Not applicable.
HMIS (U.S.A.):
Health Hazard: 2
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 2
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent.
Safety glasses.
Section 16: Other Information
References: -Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987.
Other Special Considerations: Not available.
Created: 10/09/2005 03:56 PM
Last Updated: 11/06/2008 12:00 PM