Ferric chloride MSDS

Section 1: Chemical Product and Company Identification

Product Name: Ferric chloride

Catalog Codes: SLF1675, SLF2188

CAS#: 7705-08-0

RTECS: LJ9100000

TSCA: TSCA 8(b) inventory: Ferric chloride

CI#: Not available.

Synonym:

Chemical Formula: FeCl3

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Ferric chloride 7705-08-0 100

Toxicological Data on Ingredients: Ferric chloride: ORAL (LD50): Acute: 900 mg/kg [Rat]. 1278 mg/kg [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:

Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of inhalation. Slightly

hazardous in case of skin contact (permeator). Corrosive to eyes and skin. The amount of tissue damage depends on length

of contact. Eye contact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering.

Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and

coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death.

Potential Chronic Health Effects:

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolonged

exposure to the substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust can

produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust

can produce varying degree of respiratory irritation or lung damage.

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids

open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:

If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protecting

your own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, such

as the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly

careful to clean folds, crevices, creases and groin. Cold water may be used. If irritation persists, seek medical attention. Wash

contaminated clothing before reusing.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical

attention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation:

Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If

breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It may

be hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious or

corrosive. Seek immediate medical attention.

Ingestion:

Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that

the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,

tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in

presence of static discharge: Not available.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

Section 6: Accidental Release Measures

Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue with

a dilute solution of sodium carbonate.

Large Spill:

Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray

to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.

Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentration

level above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:

Keep locked up Keep container dry. Keep away from heat. Keep away from sources of ignition. Keep away from direct sunlight

or strong incandescent light. Do not ingest. Do not breathe dust. Never add water to this product Avoid shock and friction.

Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested, seek

medical advice immediately and show the container or the label. Avoid contact with skin and eyes

Storage: Corrosive materials should be stored in a separate safety storage cabinet or room.

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended

exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants

below the exposure limit.

Personal Protection:

Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.

Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to

avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling

this product.

Exposure Limits:

TWA: 1 CEIL: 2 (mg/m3) Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid.

Odor: Not available.

Taste: Not available.

Molecular Weight: 162.21 g/mole

Color: Not available.

pH (1% soln/water): 2 [Acidic.]

Boiling Point: 316°C (600.8°F)

Melting Point: 306°C (582.8°F)

Critical Temperature: Not available.

Specific Gravity: 2.9 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: 5.61 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility: Soluble in cold water.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances:

The product may undergo hazardous decomposition, condensation or polymerization, it may react violently with water to emit

toxic gases or it may become self-reactive under conditions of shock or increase in temperature or pressure.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

Section 11: Toxicological Information

Routes of Entry: Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 900 mg/kg [Rat].

Chronic Effects on Humans: The substance is toxic to lungs, mucous membranes.

Other Toxic Effects on Humans:

Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of inhalation. Slightly hazardous in case of

skin contact (permeator).

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:

Section 14: Transport Information

DOT Classification: CLASS 8: Corrosive solid.

Identification: : Ferric chloride, anhydrous : UN1773 PG: III

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:

Pennsylvania RTK: Ferric chloride Massachusetts RTK: Ferric chloride TSCA 8(b) inventory: Ferric chloride CERCLA:

Hazardous substances.: Ferric chloride

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada):

CLASS E: Corrosive solid. CLASS F: Dangerously reactive material.

DSCL (EEC): R36/38- Irritating to eyes and skin.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

Personal Protection: j

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:

Protective Equipment:

Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear

appropriate respirator when ventilation is inadequate. Splash goggles.

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 05:32 PM

Last Updated: 11/06/2008 12:00 PM