Ferric ammonium oxalate MSDS

Ferric ammonium oxalate MSDS

 

Section 1: Chemical Product and Company Identification

Product Name: Ferric ammonium oxalate

Catalog Codes: SLF2020

CAS#: 13268-42-3

RTECS: LJ8932000

TSCA: TSCA 8(b) inventory: Ferric ammonium oxalate

CI#: Not available.

Synonym:

Chemical Name: Not available.

Chemical Formula: (NH4)3Fe(C2O4)3.3H2O

 

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Ferric ammonium oxalate 13268-42-3 100

Toxicological Data on Ingredients: Ferric ammonium oxalate LD50: Not available. LC50: Not available.

 

Section 3: Hazards Identification

Potential Acute Health Effects:

Extremely hazardous in case of inhalation. Very hazardous in case of skin contact (irritant), of eye contact (irritant), of

ingestion. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation is characterized by

itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:

Extremely hazardous in case of inhalation. Very hazardous in case of skin contact (irritant), of eye contact (irritant).

CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.

DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to kidneys, lungs, liver, mucous membranes. Repeated

or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged inhalation of dust may

lead to chronic respiratory irritation.

 

Section 4: First Aid Measures

Eye Contact:

Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids

open. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:

After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running

water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used.

Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before

reusing.

Serious Skin Contact:

Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.

Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.

Serious Inhalation: Not available.

Ingestion:

Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform

mouth-to-mouth resuscitation. Seek immediate medical attention.

Serious Ingestion: Not available.

 

Section 5: Fire and Explosion Data

Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Some metallic oxides.

Fire Hazards in Presence of Various Substances: Not available.

Explosion Hazards in Presence of Various Substances:

Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in

presence of static discharge: Not available.

Fire Fighting Media and Instructions:

SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.

 

Section 6: Accidental Release Measures

Small Spill:

Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on

the contaminated surface and dispose of according to local and regional authority requirements.

Large Spill:

Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the

contaminated surface and allow to evacuate through the sanitary system. Be careful that the product is not present at a

concentration level above TLV. Check TLV on the MSDS and with local authorities.

 

Section 7: Handling and Storage

Precautions:

Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a

fume hood. Ground all equipment containing material. Do not breathe dust. In case of insufficient ventilation, wear suitable

respiratory equipment If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skin and

eyes

Storage:

Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in a

cool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizing

agents.

 

Section 8: Exposure Controls/Personal Protection

Engineering Controls:

Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended

exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants

below the exposure limit.

Personal Protection:

Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:

Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid

inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this

product.

Exposure Limits:

TWA: 1 (mg/m3) from ACGIH Consult local authorities for acceptable exposure limits.

 

Section 9: Physical and Chemical Properties

Physical state and appearance: Solid. (Crystalline solid.)

Odor: Not available.

Taste: Not available.

Molecular Weight: 428.07 g/mole

Color: Green.

pH (1% soln/water): 5 [Acidic.]

Boiling Point: Not available.

Melting Point: Decomposes.

Critical Temperature: Not available.

Specific Gravity: 1.78 (Water = 1)

Vapor Pressure: Not applicable.

Vapor Density: Not available.

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility: Easily soluble in cold water.

 

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability: Not available.

Incompatibility with various substances: Not available.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Not available.

Special Remarks on Corrosivity: Not available.

Polymerization: No.

 

Section 11: Toxicological Information

Routes of Entry: Eye contact. Inhalation. Ingestion.

Toxicity to Animals:

LD50: Not available. LC50: Not available.

Chronic Effects on Humans: The substance is toxic to kidneys, lungs, liver, mucous membranes.

Other Toxic Effects on Humans:

Extremely hazardous in case of inhalation. Very hazardous in case of skin contact (irritant), of ingestion.

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.

 

Section 12: Ecological Information

Ecotoxicity: Not available.

BOD5 and COD: Not available.

Products of Biodegradation:

Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are more toxic.

Special Remarks on the Products of Biodegradation: Not available.

 

Section 13: Disposal Considerations

Waste Disposal:

 

Section 14: Transport Information

DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.

 

Section 15: Other Regulatory Information

Federal and State Regulations: TSCA 8(b) inventory: Ferric ammonium oxalate

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).

Other Classifications:

WHMIS (Canada): CLASS D-2A: Material causing other toxic effects (VERY TOXIC).

DSCL (EEC):

R38- Irritating to skin. R41- Risk of serious damage to eyes.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0

Personal Protection: E

National Fire Protection Association (U.S.A.):

Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:

Protective Equipment:

Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator

when ventilation is inadequate. Splash goggles.

 

Section 16: Other Information

References: Not available.

Other Special Considerations: Not available.

Created: 10/09/2005 05:32 PM

Last Updated: 11/06/2008 12:00 PM